Synthesis of Si/G Composite Anodes for Lithium-Ion Batteries: A Review

Authors

A. Azaizia ¹ , M.V. Dorogov ¹

¹ Institute of Advanced Data Transfer Systems, ITMO University, Kronverkskiy pr., 49, lit. A, St. Petersburg, 197101, Russia

10.17586/2687-0568-2024-6-4-194-213

Rev. Adv. Mater. Technol., 2024, vol. 6, no. 4, pp. 194–213

Abstract

By overcoming significant performance constraints, recent developments in silicon/graphene (Si/G) composite anodes have shown promise for revolutionizing lithium-ion batteries. Although silicon has a remarkable theoretical capacity, structural instability results from its large volume growth during cycling. Though it lacks the potential for high-energy applications, graphene, which is well-known for its exceptional mechanical flexibility and electrical conductivity, enhances the qualities of silicon. By combining these materials, Si/G composites have demonstrated impressive gains in rate performance, structural stability, and capacity retention, providing a promising avenue for next-generation energy storage technologies. High-performance Si/G composites have been made easier to create by advancements in scalable synthesis processes like sol-gel processing, chemical vapor deposition, sophisticated self-assembly techniques and Hummer’s method. With an emphasis on cutting-edge silicon-based anodes, carbon composites, and workable techniques for acquiring and altering silicon anodes, this review seeks to examine the most recent developments and unsolved issues in the advancement of lithium-ion batteries. In order to address the needs of contemporary high-capacity applications and expedite the integration of Si/G composites into next-generation energy storage systems, these insights are crucial.

Keywords

Lithium-ion batteries; Silicon-based anodes; High-capacity energy storage; Cycling stability

Foundings

RF Ministry of Science and Higher Education: 075-15-2021-1349

References

1.    J. Reslan, M. Saadaoui, T. Djenizian, Synthesis and Structural Design of Graphene, Silicon and Silicon-Based Materials Including Incorporation of Graphene as Anode to Improve Electrochemical Performance in Lithium-Ion Batteries, Adv. Mater.Interfaces, 2024, vol. 11, no. 19, pp. 1-25.
2.    H. Chang, Y.-R. Wu, X. Han, T.-F. Yi, Recent developments in advanced anode materials for lithium-ion batteries, Energy Mater., 2022,vol. 1, no. 1, art. no. 100003.
3.    M.H. Hossain, M.A. Chowdhury, N. Hossain, M.A. Islam, M.H. Mobarak, Advances of lithium-ion batteries anode materials - A review, Chem. Eng. J. Adv., 2023, vol. 16, art. no. 100569.
4.    S.K. Sharma, G. Sharma, A. Gaur, A. Arya, F.S. Mirsafi, R. Abolhassani, H.-G.Rubahn, J.-S.Yu,Y.K. Mishra, Progress in electrode and electrolyte materials: path to all-solid-state Li-ion batteries, Energy Adv., 2022, vol. 1, no. 8, pp. 457-510.
5.    E. Podlesnov, M.G. Nigamatdianov, M.V. Dorogov, Review of Materials for Electrodes and Electrolytes of Lithium Batteries, Rev. Adv. Mater. Technol., 2022, vol. 4, no. 4, pp. 39-61.
6.    A. Eftekhari, Low voltage anode materials for lithium-ion batteries, Energy Storage Mater., 2017, vol. 7, pp. 157-180.
7.    P.U. Nzereogu, A.D. Omah, F.I. Ezema, E.I. Iwuoha, A.C. Nwanya, Anode materials for lithium-ion batteries: A review, Appl. Surf. Sci. Adv., 2022, vol. 9, art. no. 100233.
8.    L. Ji, Z. Lin, M. Alcoutlabi, X. Zhang, Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries, Energy Environ. Sci., 2011, vol. 4, no. 8, pp. 2682-2689.
9.    J.K. Lee, C. Oh, N. Kim, J.Y. Hwang, Y.K. Sun, Rational design of silicon-based composites for high-energy storage devices, J. Mater. Chem. A, 2016, vol. 4, no. 15, pp. 5366-5384.
10.    H.J. Kim, T. Krishna, K. Zeb, V.Rajangam, C.V.V.M. Gopi, S. Sambasivam, K.V.G. Raghavendra, I.M. Obaidat, A comprehensive review of li-ion battery materials and their recycling techniques, Electronics, 2020, vol. 9, no. 7., art. no. 1161.
11.    A.R. Kamali, D.J. Fray, Tin-based materials as advanced anode materials for lithium ion batteries: A review, Rev. Adv. Mater. Sci., 2011, vol. 27, no. 1, pp. 14-24.
12.    G.F.I. Toki, M.K. Hossain, W.U. Rehman, R.Z.A. Manj, L. Wang, J. Yang, Recent progress and challenges in silicon-based anode materials for lithium-ion batteries, Ind. Chem. Mater., 2024, vol. 2, no. 2, pp. 226-269.
13.    Si/C Composites for Battery Materials, Electronic resource, URL: https://www.acsmaterial.com/blog-detail/sic-composites-for-battery-materials.html (accessed: 03.12.2024).
14.    A. Ulvestad, J.P. Mæhlen, M. Kirkengen, Silicon nitride as anode material for Li-ion batteries: Understanding the SiNx conversion reaction, J. Power Sources, 2018, vol. 399, no. 2027, pp. 414-421.
15.    M. Nie, D.P. Abraham, Y. Chen, A. Bose, B.L. Lucht, Silicon solid electrolyte interphase (SEI) of lithium ion battery characterized by microscopy and spectroscopy, J. Phys. Chem. C, 2013, vol. 117, no. 26, pp. 13403-13412.
16.    E. Feyzi, A. Kumar M R, X. Li, S. Deng, J. Nanda, K. Zaghib, A comprehensive review of silicon anodes for high-energy lithium-ion batteries: Challenges, latest developments, and perspectives, Next Energy, 2024, vol. 5, art. no. 100176.
17.    T.Vorauer, J.Schöggl, S.G. Sanadhya, M. Poluektov, W.D. Widanage, L. Figiel, S. Schädler, B. Tordoff, B. Fuchsbichler, S. Koller, R. Brunner, Impact of solid-electrolyte interphase reformation on capacity loss in silicon-based lithium-ion batteries, Commun. Mater., 2023, vol. 4, no. 1, art. no. 44.
18.    X. Zhang, J. Weng, C. Ye, M. Liu, C. Wang, S. Wu, Q. Tong, M. Zhu, F. Gao, Strategies for Controlling or Releasing the Influence Due to the Volume Expansion of Silicon inside Si-C Composite Anode for High-Performance Lithium-Ion Batteries, Materials, 2022, vol. 15, no. 12, art. no. 4264.
19.    C. Zhang, F. Wang, J. Han, S. Bai, J. Tan, J. Liu, F. Li, Challenges and Recent Progress on Silicon-Based Anode Materials for Next-Generation Lithium-Ion Batteries, Small Struct., 2021, vol. 2, no. 6, art. no. 2100009.
20.    F. De Santiago, J.E. González, A. Miranda, A. Trejo, F. Salazar, L.A. Pérez, M. Cruz-Irisson, Lithiation effects on the structural and electronic properties of Si nanowires as a potential anode material, Energy Storage Mater., 2019, vol. 20, pp. 438-445.
21.    C. Yang, K.S.R. Chandran, A critical review of silicon nanowire electrodes and their energy storage capacities in Li-ion cells, RSC Adv., 2023, vol. 13, no. 6, pp. 3947-3957.
22.    X. Li, M. Wu, T. Feng, Z. Xu, J. Qin, C. Chen, C. Tu, D. Wang, Graphene enhanced silicon/carbon composite as anode for high performance lithium-ion batteries, RSC Adv., 2017, vol. 7, no. 76, pp. 48286-48293.
23.    B.A. Nuhu, O. Bamisile, H. Adun, U.O. Abu, D. Cai, Effects of transition metals for silicon-based lithium-ion battery anodes: A comparative study in electrochemical applications, J. Alloys Compd., 2023, vol. 933, art. no. 167737.
24.    P. Hu, M. Dorogov, Y. Xin, K.E. Aifantis, Transforming Single-Crystal CuO/Cu2O Nanorods into Nano-Polycrystalline Cu/Cu2O through Lithiation, ChemElectroChem, 2019, vol. 6, no. 12, pp. 3139-3144.
25.    W. Wang, M.K. Datta, P.N. Kumta, Silicon-based composite anodes for Li-ion rechargeable batteries, J. Mater. Chem., 2007, vol. 17, no. 30, pp. 3229-3237.
26.    M. Nigamatdianov, N. Chirkunova, M. Dorogov, Belt-like SnO2 structures for lithium batteries, AIP Conf. Proc., 2022, vol. 2533, no. 1, art. no. 020010.
27.    T. Insinna, E. N. Bassey, K. Märker, A. Collauto, A.L. Barra, C.P. Grey, Graphite Anodes for Li-Ion Batteries: An Electron Paramagnetic Resonance Investigation, Chem. Mater., 2023, vol. 35, no. 14, pp. 5497-5511.
28.    Silicon/Carbon (Si/C) Composite Anode Materials, Electronic resource, URL: https://www.novarials.com/products/silicon-carbon-composite-anode-materials/(accessed: 03.12.2024).
29.    Z. Chen, I. Belharouak, Y.K. Sun, K. Amine, Titanium-based anode materials for safe lithium-ion batteries, Adv. Funct. Mater., 2013, vol. 23, no. 8, pp. 959-969.
30.    L. Zhong, C. Beaudette, J. Guo, K. Bozhilov, L. Mangolini, Tin nanoparticles as an effective conductive additive in silicon anodes, Sci. Rep., 2016, vol. 6, art. no. 30952.
31.    A.G. Hailu, A. Ramar, F.-M. Wang, N.-H. Yeh, P.-W. Tiong, C.-C. Hsu, Y.-J. Chang, M.-M. Chen, T.-W. Chen, C.-C. Wang, B.A. Kahsay, L. Merinda, The development of super electrically conductive Si material with polymer brush acid and emeraldine base and its auto-switch design for high-safety and high-performance lithium-ion battery, Electrochim. Acta, 2022, vol. 429, art. no. 140829.
32.    Y. Javadzadeh, S. Hamedeyaz, Floating Drug Delivery Systems for Eradication of Helicobacter pylori in Treatment of Peptic Ulcer Disease, in: B. Roesler (Eds.), Trends in Helicobacter pylori Infection, InTech, 2014, pp. 303-319.
33.    D. Lou, S. Chen, S. Langrud, A.A. Razzaq, M. Mao, H. Younes, W. Xing, T. Lin, H. Hong, Scalable Fabrication of Si-Graphene Composite as Anode for Li-ion Batteries, Appl. Sci., 2022, vol. 12, no. 21, art. no. 10926.
34.    J.C. Hestenes, J.T. Sadowski, R. May, L.E. Marbella, Transition Metal Dissolution Mechanisms and Impacts on Electronic Conductivity in Composite LiNi0.5Mn1.5O4 Cathode Films, ACS Mater. Au, 2023, vol. 3, no. 2, pp. 88-101.
35.    H. Huo, M. Jiang, Y. Bai, S. Ahmed, K. Volz, H. Hartmann, A. Henss, C.V. Singh, D. Raabe, J. Janek, Chemo-mechanical failure mechanisms of the silicon anode in solid-state batteries, Nat. Mater., 2024, vol. 23, no. 4, pp. 543-551.
36.    S.K. Kim, H. Kim, H. Chang, B.-G. Cho, J. Huang, H. Yoo, H. Kim, H.D. Jang, One-Step Formation of Silicon-Graphene Composites from Silicon Sludge Waste and Graphene Oxide via Aerosol Process for Lithium Ion Batteries, Sci. Rep., 2016, vol. 6, art. no. 33688.
37.    G.G. Eshetu, H. Zhang, X. Judez, H. Adenusi, M. Armand, S. Passerini, E. Figgemeier, Production of high-energy Li-ion batteries comprising silicon-containing anodes and insertion-type cathodes, Nat.Commun., 2021, vol. 12, art. no. 5459.
38.    J. Saddique, M. Wu, W. Ali, X. Xu, Z.-G. Jiang, L. Tong, H. Zheng, W. Hu, Opportunities and challenges of nano Si/C composites in lithium ion battery: A mini review, J. Alloys Compd., 2024, vol. 978, art. no. 173507.
39.    M. Khan, S. Yan, M. Ali, F. Mahmood, Y. Zheng, G. Li, J. Liu, X. Song, Y. Wang, Innovative Solutions for High-Performance Silicon Anodes in Lithium-Ion Batteries: Overcoming Challenges and Real-World Applications, Nano-Micro Lett., 2024. vol. 16, art. no. 179.
40.    J. Liang, Y. Xu, H. Sun, X. Xu, T. Liu, H. Liu, H. Wang, Vacuum-Dried 3D Holey Graphene Frameworks Enabling High Mass Loading and Fast Charge Transfer for Advanced Batteries, Energy Technol., 2020, vol. 8, no. 3, art. no. 1901002.
41.    Y. Cen, R. Sisson, Q. Qin, J. Liang, Current Progress of Si/Graphene Nanocomposites for Lithium-Ion Batteries, C, 2018, vol. 4, no. 1, art. no. 18.
42.    M. Jiao, Y. Wang, C. Ye, C. Wang, W. Zhang, C. Liang, High-capacity SiOx (0≤x≤2) as promising anode materials for next-generation lithium-ion batteries, J. Alloys Compd., 2020, vol. 842, art. no. 155774.
43.    Q. Zhang, N.-J. Song, C.-L. Ma, Y. Zhao, Y. Li, J. Li, X.-M. Li, Q.-Q. Kong, C.-M. Chen, Constructing a Low-Cost Si-NSs@C/NG Composite by a Ball Milling-Catalytic Pyrolysis Method for Lithium Storage, Molecules, 2023, vol. 28, no. 8, art. no. 3458.
44.    M. Gauthier, D. Mazouzi, D. Reyter, B. Lestriez, P. Moreau, D. Guyomard, L. Roué, A low-cost and high performance ball-milled Si-based negative electrode for high-energy Li-ion batteries, Energy Environ. Sci., 2013, vol. 6, no. 7, pp. 2145-2155.
45.    Q. Shi, J. Zhou, S. Ullah, X. Yang, K. Tokarska, B. Trzebicka, H.Q. Ta, M.H. Rümmeli, A review of recent developments in Si/C composite materials for Li-ion batteries, Energy Storage Mater., 2021, vol. 34, pp. 735-754.
46.    Y. Cui, X. Duan, J. Hu, C.M. Lieber, Doping and Electrical Transport in Silicon Nanowires, J. Phys. Chem. B, 2000, vol. 104, no. 22, pp. 5213-5216.
47.    W. Ren, Y. Wang, Z. Zhang, Q. Tan, Z. Zhong, F. Su, Carbon-coated porous silicon composites as high performance Li-ion battery anode materials: Can the production process be cheaper and greener?, J. Mater. Chem. A, 2015, vol. 4, no. 2, pp. 552-560.
48.    A. Magasinski, P. Dixon, B. Hertzberg, A. Kvit, J. Ayala, G. Yushin, High-performance lithium-ion anodes using a hierarchical bottom-up approach, Nat. Mater., 2010, vol. 9, no. 4, pp. 353-358.
49.    L.M. Dorogin, M.V. Dorogov, S. Vlassov, A.A. Vikarchuk, A.E. Romanov, Whisker Growth and Cavity Formation at the Microscale, Rev. Adv. Mater. Technol., 2020, vol. 2, no. 1, pp. 1-31.
50.    M. Dorogov, A. Kalmykov, L. Sorokin, A. Kozlov, A. Myasoedov, D. Kirilenko, N. Chirkunova, A. Priezzheva, A. Romanov, E.C. Aifantis, CuO nanowhiskers: preparation, structure features, properties, and applications, Mater. Sci. Technol., 2018, vol. 34, no. 17, pp. 2126-2135.
51.    E. Podlesnov, M.V. Dorogov, Nanowhiskers for lithium battery anode, IOP Conf. Ser.: Mater. Sci. Eng., 2020, vol. 1008, art. no. 012043.
52.    A.R. Urade, I. Lahiri, K.S. Suresh, Graphene Properties, Synthesis and Applications: A Review, JOM, 2023, vol. 75, no. 3, pp. 614-630.
53.    Z. Liu, Y. Tian, P. Wang, G. Zhang, Applications of graphene-based composites in the anode of lithium-ion batteries, Front. Nanotechnol., 2022, vol. 4, art. no. 952200.
54.    A. Islam, B. Mukherjee, K.K. Pandey, A.K. Keshri, Ultra-Fast, Chemical-Free, Mass Production of High Quality Exfoliated Graphene, ACS Nano, 2021, vol. 15, no. 1, pp. 1775-1784.
55.    A.R.R. Hernández, A.G. Cruz, J. Campos-Delgado, Chemical Vapor Deposition Synthesis of Graphene on Copper Foils, in: M. Ikram, A. Maqsood, A. Bashir (Eds.), Graphene - A Wonder Material for Scientists and Engineers, IntechOpen, 2023, pp. 1-16.
56.    CVD Graphene | Technology | Chemical Vapor Deposition Graphene, URL: https://generalgraphenecorp.com/technology/(accessed: 03.12.2024).
57.    K. Rana, S.D. Kim, J.-H. Ahn, Additive-free thick graphene film as an anode material for flexible lithium-ion batteries, Nanoscale, 2015, vol. 7, no. 16, pp. 7065-7071.
58.    I. Imae, K. Yukinaga, K. Imato, Y. Ooyama, Y. Kimura, Facile silicon / graphene composite synthesis method for application in lithium-ion batteries, Ceram.Int., 2022, vol. 48, no. 17, pp. 25439-25444.
59.    P.B. Zhang, Y. You, C. Wang, X.H. Fang, W. Ren, L.Y. Yang, X.Y. Chen, A novel anode material for lithium-ion batteries: silicon nanoparticles and graphene composite films, IOP Conf. Ser.: Earth Environ. Sci., 2019, vol. 354, art. no. 12079.
60.    J.K. Lee, K.B. Smith, C.M. Hayner, H.H. Kung, Silicon nanoparticles-graphene paper composites for Li ion battery anodes, Chem.Commun., 2010, vol. 46, no. 12, pp. 2025-2027.
61.    Y. Ye, X. Xie, J. Rick, F. Chang, B. Hwang, Improved anode materials for lithium-ion batteries comprise non-covalently bonded graphene and silicon nanoparticles, J. Power Sources, 2014, vol. 247, pp. 991-998.
62.    D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev, L.B. Alemany, W. Lu, J.M. Tour, Improved synthesis of graphene oxide, ACS Nano, 2010, vol. 4, no. 8, pp. 4806-4814.
63.    L. Niu, Q. Zhang, R. Zhang, D. Wang, G. Wen, L. Qin, Modulating functional groups of GO to improve the electrochemical performance of Si/rGO anode, Colloids Surf. A Physicochem. Eng. Asp., 2024, vol. 691, art. no. 133877.
64.    W.S. Hummers Jr., R.E. Offeman, Preparation of graphitic oxide, J. Am. Chem. Soc., 1958, vol. 80, no. 6, p. 1339.
65.    Y. Du, G. Zhu, K. Wang, Y. Wang, C. Wang, Y. Xia, Si/graphene composite prepared by magnesium thermal reduction of SiO2 as anode material for lithium-ion batteries, Electrochem.Commun., 2013, vol. 36, pp. 107-110.
66.    M.-S. Wang, Z.-Q. Wang, R. Jia, Y. Yang, F.-Y. Zhu, Z.-L. Yang, Y. Huang, X. Li, W. Xu, Facile electrostatic self-assembly of silicon/reduced graphene oxide porous composite by silica assist as high performance anode for Li-ion battery, Appl. Surf. Sci., 2018, vol. 456, pp. 379-389.
67.    X. Zhang, D. Wang, X. Qiu, Y. Ma, D. Kong, K. Müllen, X. Li, L. Zhi, Stable high-capacity and high-rate silicon-based lithium battery anodes upon two-dimensional covalent encapsulation, Nat.Commun., 2020, vol. 11, art. no. 3826.
68.    W. Zhang, S. Gui, W. Li, S. Tu, G. Li, Y. Zhang, Y. Sun, J. Xie, H. Zhou, H. Yang, Functionally gradient silicon/graphite composite electrodes enabling stable cycling and high capacity for lithium-ion batteries, ACS Appl. Mater.Interfaces, 2022, vol. 14, no. 46, pp. 51954-51964.
69.    S. Kaushik, T. Mehta, P. Chand, S. Sharma, G. Kumar, Recent advancements in cathode materials for high-performance Li-ion batteries: Progress and prospects, J. Energy Storage, 2024, vol. 97, part A, art. no. 112818.
70.    What Are Battery Anode and Cathode Materials? - AquaMetals, Electronic resource, URL: https://aquametals.com/recyclopedia/lithium-ion-anode-and-cathode-materials/(accessed: 03.12.2024).
71.    Cost-effective, high-capacity, and cyclable lithium-ion battery cathodes, Electronic resource, URL: https://www.sciencedaily.com/releases/2024/05/240502141245.htm (accessed: 03.12.2024).
72.    Y. Lu, H. Han, Z. Yang, Y. Ni, Z. Meng, Q. Zhang, H. Wu, W. Xie, Z. Yan, J. Chen, High-capacity dilithium hydroquinone cathode material for lithium-ion batteries, National Science Review, 2024, vol. 11, no. 6, art. no. nwae146.
73.    J. Li, X. Zhang, R. Peng, Y. Huang, L. Guo, Y. Qi, LiMn2O4/graphene composites as cathodes with enhanced electrochemical performance for lithium-ion capacitors, RSC Adv., 2016, vol. 6, no. 60, pp. 54866-54873.
74.    R. Hu, W. Sun, Y. Chen, M. Zeng, M. Zhu, Silicon/graphene based nanocomposite anode: large-scale production and stable high capacity for lithium ion batteries, J. Mater. Chem. A, 2014, vol. 2, no. 24, pp. 9118-9125.
75.    M.J. Loveridge, M.J. Lain, I.D. Johnson, A. Roberts, S.D. Beattie, R. Dashwood, J.A. Darr, R. Bhagat, Towards high capacity Li-ion batteries based on silicon-graphene composite anodes and sub-micron V-doped LiFePO4 cathodes, Sci. Rep., 2016, vol. 6, no. 1, art. no. 37787.
76.    M. Je, D.-Y. Han, J. Ryu, S. Park, Constructing pure Si anodes for advanced lithium batteries, Acc. Chem. Res., 2023, vol. 56, no. 16, pp. 2213-2224.
77.    M.S. Ahmed, M. Islam, B. Raut, S. Yun, H. Y. Kim, K.-W. Nam, A Comprehensive Review of Functional Gel Polymer Electrolytes and Applications in Lithium-Ion Battery, Gels, 2024, vol. 10, no. 9, art. no. 563.
78.    J. Asenbauer, T. Eisenmann, M. Kuenzel, A. Kazzazi, Z. Chen, D. Bresser, The success story of graphite as a lithium-ion anode material-fundamentals, remaining challenges, and recent developments including silicon (oxide) composites, Sustain. Energy Fuels, 2020, vol. 4, no. 11, pp. 5387-5416.
79.    E. Zhao, Y. Gu, S. Fang, L. Yang, S. Hirano, Systematic investigation of electrochemical performances for lithium-ion batteries with Si/Graphite anodes: effect of electrolytes based on fluoroethylene carbonate and linear carbonates, ACS Appl. Energy Mater., 2021, vol. 4, no. 3, pp. 2419-2429.
80.    K. Yao, J. P. Zheng, R. Liang, Ethylene carbonate-free fluoroethylene carbonate-based electrolyte works better for freestanding Si-based composite paper anodes for Li-ion batteries, J. Power Sources, 2018, vol. 381, pp. 164-170.
81.    E. Podlesnov, M.G. Nigamatdianov, A.O. Safronova, M.V. Dorogov, Lithium Polymer Battery with PVDF-based Electrolyte Doped with Copper Oxide Nanoparticles: Manufacturing Technology and Properties, Rev. Adv. Mater. Technol., 2021, vol. 3 no 3, pp. 27-31.

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Receive Date: 03 December 2024

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Available online: 30 December 2024

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