ISSN 2687-0568

Effect of Aluminum Content on Lattice Parameters and Unit Cell Volume in Bulk Crystals β-(AlxGa1–x)2O3

Authors
D.A. Bauman 1 , D.I. Panov 1 , V.A. Spiridonov 1 , A.Y. Ivanov 1 , M.A. Yagovkina 2 , A.E. Romanov 1, 2

1 Institute of Advanced Data Transfer Systems, ITMO University, Kronverkskiy pr., 49, lit. A, St. Petersburg, 197101, Russia

2 Ioffe Physical-Technical Institute RAS, St. Petersburg, 194021, Russia

Rev. Adv. Mater. Technol., 2024, vol. 6, no. 4, pp. 189–193
Abstract

The article studies the influence of aluminum on the lattice parameters and the unit cell volume of the binary solid solution β-(AlxGa1–x)2O3. The aluminum content is determined by energy-dispersive X-ray spectroscopy. The lattice parameter values are calculated using X-ray diffractometry data. The diffraction patterns show peak broadening and shift to higher angles with increasing aluminum content. It is shown that when the aluminum fraction x changes from 0 to 0.25, the lattice parameters decrease linearly. This is consistent with Vegard’s law for solid solutions. The decrease in cell volume is physically related to the fact that aluminum has a smaller ionic radius than gallium, and the Al–O bond length is shorter than Ga–O one.

Keywords
Aluminum gallium oxide; Bulk crystal; Unit cell; Lattice parameters
Foundings

Ministry of Science and Higher Education of the Russian Federation: 075-15-2021-1349

References
Volume 6, No 4
pages 189-193
History
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