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Методы химического синтеза для контроля морфологии и получения однородных массивов металлических наночастиц в полупроводниковых пленках
Авторы
Л.А. Сокура 1, 2 , A. M. Smirnov 1 , А.Е. Романов 1, 2, 31 Институт перспективных систем передачи данных, Университет ИТМО, Кронверкский пр., д. 49 лит. А, 197101, Санкт-Петербург, Россия
2 Физико-технический институт им. А.Ф. Иоффе РАН, Политехническая ул., 26, Санкт-Петербург, 194021, Россия
3 Changchun University of Science and Technology, Weixing Rd., No.7989, Changchun, Jilin 130022, China
Аннотация
На оптические свойства металлических наночастиц существенное влияние оказывает их морфология, и изменение их формы приводит к появлению ряда интересных свойств. Наличие острых краев и вершин у наночастиц несферической формы, а именно формы многогранника, например, пентагональной и, в частности, икосаэдрической, приводит к лучшей локализации электрического поля в наночастице. Уникальные оптические и электрические свойства наночастиц и полупроводниковых пленок с внедренными наночастицами делают их перспективными для различных применений, включая фотовольтаику, оптоэлектронику и светоизлучающие устройства. Поскольку свойства нанокомпозитов на основе наночастиц определяются не только морфологией наночастиц, но и их распределением в объеме пленки, необходимо разработать методы получения наночастиц с возможностью контроля и варьирования их морфологии, а также их введения в полупроводниковые пленки для получения однородных массивов. В этой статье дается обзор соответствующих исследований, основное внимание в которых уделяется химическому синтезу, как одному из наиболее распространенных методов получения металлических наночастиц.
Ключевые слова
нанокомпозиты; металлические и полупроводниковые наночастицы; морфология наночастиц; химический синтезФинансирование
Russian Science Foundation: 23-72-10014.
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